Mesoporous nitrogen-doped TiO2 sphere applied for quasi-solid-state dye-sensitized solar cell
نویسندگان
چکیده
A mesoscopic nitrogen-doped TiO2 sphere has been developed for a quasi-solid-state dye-sensitized solar cell [DSSC]. Compared with the undoped TiO2 sphere, the quasi-solid-state DSSC based on the nitrogen-doped TiO2 sphere shows more excellent photovoltaic performance. The photoelectrochemistry of electrodes based on nitrogen-doped and undoped TiO2 spheres was characterized with Mott-Schottky analysis, intensity modulated photocurrent spectroscopy, and electrochemical impedance spectroscopy, which indicated that both the quasi-Fermi level and the charge transport of the photoelectrode were improved after being doped with nitrogen. As a result, a photoelectric conversion efficiency of 6.01% was obtained for the quasi-solid-state DSSC.
منابع مشابه
Synthesis and characterization of Ag-doped TiO2 nanostructure and investigation of its application as dye-sensitized solar cell
A new strategy for enhancing the efficiency of TiO2 dye-sensitized solar cells (DSSCs) by doping foreign ion into TiO2 lattice via sol-gel process is reported. DSSCs are based on a semiconductor (i.e., TiO2), formed between a photo-sensitized anode and an electrolyte. In order to reach high conversion efficiency, it is important to increase the electron injection and optical absorption. One pro...
متن کاملComparison of Transparent Nickel Doped Cobalt Sulfide and Platinum Counter Electrodes Used in Quasi-Solid State Dye Sensitized Solar Cells
Transparent nickel doped cobalt sulfide was fabricated on a SnO2:F electrode and tested as an efficient electrocatalyst and as an alternative to the expensive platinum counter electrode. In order to investigate how this electrode could affect the electrical characteristics of a dye-sensitized solar cell, we manufactured cells with the same TiO2 photoanode sensitized with dye (N719) and employin...
متن کاملFabrication of dye sensitized solar cells with a double layer photoanode
Dye sensitized solar cell was fabricated from a double layer photoanode. First, TiO2 nanoparticles were synthesized by hydrothermal method. These TiO2 NPs were deposited on FTO glasses by electrophoretic deposition method in applied voltage of 5 V and EPD time of 2.5-10 min. Then TiO2 hollow spheres (HSs) were synthesized by sacrificed template method with Carbon Spheres as template and TTIP ...
متن کاملFabrication of Novel High Potential Chromium-Doped TiO2 Nanoparticulate Electrode-based Dye-Sensitized Solar Cell (DSSC)
In the current study, pure TiO2 and Cr-doped TiO2 (Cr@TiO2) nanoparticles were synthesized via sol-gel method and the resulting materials were applied to prepare the porous TiO2 electrodes for dye-sensitized solar cells (DSSCs). It is hypothesized that the advantages of the doping of the metal ions into TiO2 lattice are the temporary rapping of the photogenerated electron-hole (charge carriers)...
متن کاملGraft copolymer directed synthesis of micron-thick organized mesoporous TiO2 films for solid-state dye-sensitized solar cells.
Micron thick, well-organized mesoporous TiO(2) films with high porosity and good connectivity were synthesized by templating an amphiphilic graft copolymer for solid-state dye-sensitized solar cells.
متن کامل